Google introduced a custom print dialog to Chrome a few versions ago. This adds a step to saving a PDF or using any of the other standard options. Until recently, this could be disabled in chrome://flags/. They have since removed the flag, but they did leave the command line option to disable it.
A workaround is to create an AppleScript applet that launches Chrome with this option. The following script does exactly that, assuming Chrome is located in your applications folder:
do shell script "/Applications/Google\\ Chrome.app/Contents/MacOS/Google\\ Chrome --args --disable-print-preview > /dev/null 2>&1 &"
Open AppleScript Editor, paste the above into a new window, then save it as an application. If you run this applet to launch Chrome, you'll get a standard Print dialog (though interestingly it's a dialog window, not a sheet).