There is no preset keyboard shortcut for Notification Center, but you can set one in System Preferences > Keyboard > Keyboard Shortcuts > Mission Control.
[kirkmc adds: You can also set a hot corner in the Mission Control preference pane. I find the top-right hot corner to be ideal.]
[kirkmc adds: You can also set a hot corner in the Mission Control preference pane. I find the top-right hot corner to be ideal.]
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